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Tier 3 — Observational / field trialPeer-reviewed

Abiologic silicon isotope fractionation between aqueous Si and Fe(III)–Si gel in simulated Archean seawater: Implications for Si isotope records in Precambrian sedimentary rocks

Xin‐Yuan Zheng, Brian L. Beard, Thiruchelvi R. Reddy, Eric Roden, Clark M. Johnson

Geochimica et Cosmochimica Acta · 2016

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Summary

This laboratory study experimentally determined the abiological fractionation of silicon isotopes between dissolved silica and iron(III)–silica gel precipitates under conditions simulating Archean seawater chemistry. The work provides a geochemical framework for interpreting silicon isotope records preserved in Precambrian sedimentary rocks, helping to distinguish abiological from potential biologically-mediated isotopic fractionation in ancient marine environments.

UK applicability

This study is fundamentally a palaeochemistry and isotope geochemistry contribution with limited direct applicability to UK farming, soil, or food systems. It addresses understanding of deep time Earth processes rather than contemporary agricultural or nutritional outcomes.

Key measures

Silicon isotope fractionation factors (Δ30Si) between aqueous Si and Fe(III)–Si gel phases; silicon isotope ratios in experimental products

Outcomes reported

The study experimentally determined silicon isotope fractionation factors between aqueous silicon and iron(III)–silicon gels under simulated Archean seawater conditions. Results are used to interpret silicon isotope signatures preserved in Precambrian sedimentary rocks.

Theme
Measurement & metrics
Subject
Other / interdisciplinary
Study type
Research
Study design
Laboratory / in vitro
Source type
Peer-reviewed study
Status
Published
Geography
United States
System type
Laboratory / in vitro
DOI
10.1016/j.gca.2016.05.012
Catalogue ID
BFmommplpq-xmzqq8

Topic tags

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